Rice flash Joule heating process recycles plastic from end-of-life F-150 trucks into high-value graphene for new vehicles – Green Car Congress
Rice University chemists working with researchers at the Ford Motor Company are turning plastic parts from end-of-life vehicles into graphene via the university’s flash Joule heating process (earlier post). The Rice lab of chemist James Tour introduced flash Joule heating in 2020 to convert coal, petroleum coke and trash into graphene. The lab has since adapted the process to convert plastic waste into graphene and to extract precious metals from electronic waste.
The average SUV contains up to 350 kilograms (771 pounds) of plastic that could sit in a landfill for centuries but for the recycling process reported in an open-access paper in the debut issue of a new Nature journal, Communications Engineering.
The goal of the project led by Tour and graduate student and lead author Kevin Wyss was to reuse that graphene to make enhanced polyurethane foam for new vehicles. Tests showed the graphene-infused foam had a 34% increase in tensile strength and a 25% increase in low-frequency noise absorption. That’s with only 0.1% by weight or less of graphene.
When that new car is old, the foam can be flashed into graphene again.
Ford sent us 10 pounds of mixed plastic waste from a vehicle shredding facility. It was muddy and wet. We flashed it, we sent the graphene back to Ford, they put it into new foam composites and it did everything it was supposed to do. Then they sent us the new composites and we flashed those and turned them back into graphene. It’s a great example of circular recycling.
The researchers cited a study that estimates the amount of plastic used in vehicles has increased by 75% in just the past six years as a means to reduce weight and increase fuel economy.
Segregating mixed end-of-life plastic by type for recycling has been a long-term problem for the auto industry, Tour said, and it’s becoming more critical because of potential environmental regulations around end-of-life vehicles.
In Europe, cars come back to the manufacturer, which is allowed to landfill only 5% of a vehicle,. That means they must recycle 95%, and it’s just overwhelming to them.
Much of the mixed plastic ends up being incinerated, according to co-author Deborah Mielewski, technical fellow for sustainability at Ford, who noted the US shreds 10 to 15 million vehicles each year, with more than 27 million shredded globally.
We have hundreds of different combinations of plastic resin, filler and reinforcements on vehicles that make the materials impossible to separate. Every application has a specific loading/mixture that most economically meets the requirements.
Flash Joule heating to make graphene packs mixed ground plastic and a coke additive (for conductivity) between electrodes in a tube and blasts it with high voltage. The sudden, intense heat—up to nearly 5,000 degrees Fahrenheit—vaporizes other elements and leaves behind easy-to-solubilize, turbostratic graphene.
Flash heating offers significant environmental benefits, as the process does not require solvents and uses a minimum of energy to produce graphene.
To test whether end-of-life, mixed plastic could be transformed, the Rice lab ground the shredder fluff made of plastic bumpers, gaskets, carpets, mats, seating and door casings from end-of-life F-150 pickup trucks to a fine powder without washing or pre-sorting the components.
The lab flashed the powder in two steps, first under low current and then high current in a heater Wyss custom designed for the experiment.